trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

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Atıf İçin Kopyala

YILMAZ V. T., Guney S., KAZAK C.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.64, 2008 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 64
• Basım Tarihi: 2008
• Doi Numarası: 10.1107/s1600536807062745
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Bursa Uludağ Üniversitesi Adresli: Evet

Özet

In the centrosymmetric title complex, [Co(C7H4NO3S)(2)(C6H15N3)(2)], the Co-II ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N'-bidentate chelating ligand. The molecules are connected by N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.