Efficient and chemoselective alkyl bromoacetate-Zn mediated transesterification method
TETRAHEDRON, vol.59, no.19, pp.3481-3485, 2003 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 59 Issue: 19
- Publication Date: 2003
- Doi Number: 10.1016/s0040-4020(03)00472-1
- Journal Name: TETRAHEDRON
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.3481-3485
- Keywords: chemoselective transesterification, Reformatsky reagent, IMIDAZOLINE 3-OXIDES, DIASTEREOSELECTIVE ADDITION, REGIO
- Bursa Uludag University Affiliated: Yes
Abstract
Alkyl bromoacetates were shown to be versatile transesterification reagents. Isoxazoles underwent chemoselective transesterification when treated with alkyl bromoacetate-Zn in THF at reflux. A suggested mechanism of the new reaction was discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.