Concentrations, phase exchanges and source apportionment of polycyclic aromatic hydrocarbons (PAHs) In Bursa-Turkey

Sanli G., Celik S., Joubi V., TAŞDEMİR Y.

Environmental Research, cilt.232, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 232
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.envres.2023.116344
  • Dergi Adı: Environmental Research
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Applied Science & Technology Source, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, CAB Abstracts, Chemical Abstracts Core, Communication Abstracts, Computer & Applied Sciences, EMBASE, Environment Index, Geobase, Greenfile, MEDLINE, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Air-plant exchage, Air-soil exchange, Partitioning, Passive air sampler, Soil-plant exchange, Tree
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

The present study aimed to determine the pollution levels derived from polycyclic aromatic hydrocarbons (PAHs) in air, plant and soil samples and to reveal the PAH exchange at the soil-air, soil-plant and plant-air interfaces. In this context, air and soil samples were collected in approximately 10-day periods between June 2021 and February 2022 from a semi-urban area in Bursa, an industrial city with a dense population. Also, plant branch samples were collected for the last three months. Total PAH concentrations in the atmosphere (∑16PAH) and soil (∑14PAH) ranged from 4.03 to 64.6 ng/m3 and 13–189.4 ng/g DM, respectively. PAH levels in the tree branches varied between 256.6 and 419.75 ng/g DM. In all air and soil samples, PAH levels were low in the summer and reached higher values in the winter. 3-ring PAHs were the dominant compounds, and their distribution in air and soil samples varied between 28.9%-71.9% and 22.8%–57.7%, respectively. According to the results of diagnostic ratios (DRs) and principal component analysis (PCA), both pyrolytic and petrogenic sources were found to be effective in PAH pollution in the sampling region. The fugacity fraction (ff) ratio and net flux (Fnet) values indicated that the direction of movement of PAHs was from soil to air. In order to better understand the PAH movement in the environment, soil-plant exchange calculations were also achieved. The ratio of ∑14PAH values measured to modeled concentrations (1.19