The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids


TAVASLI M. , O'Hagan D., Pearson C., Petty M.

CHEMICAL COMMUNICATIONS, no.11, pp.1226-1227, 2002 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 11
  • Publication Date: 2002
  • Doi Number: 10.1039/b202891c
  • Title of Journal : CHEMICAL COMMUNICATIONS
  • Page Numbers: pp.1226-1227

Abstract

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.