The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids

TAVASLI, MUSTAFA; O'Hagan, D; Pearson, C; Petty, MC

doi:10.1039/b202891c

The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids

TAVASLI M., O'Hagan D., Pearson C., Petty M.

CHEMICAL COMMUNICATIONS, sa.11, ss.1226-1227, 2002 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: Sayı: 11
Basım Tarihi: 2002
Doi Numarası: 10.1039/b202891c
Dergi Adı: CHEMICAL COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1226-1227
Bursa Uludağ Üniversitesi Adresli: Hayır

Özet

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.