The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids

TAVASLI M., O'Hagan D., Pearson C., Petty M.

CHEMICAL COMMUNICATIONS, no.11, pp.1226-1227, 2002 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 11
  • Publication Date: 2002
  • Doi Number: 10.1039/b202891c
  • Journal Name: CHEMICAL COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1226-1227
  • Bursa Uludag University Affiliated: No

Abstract

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.