Atıf İçin Kopyala
YILDIRIM A., Kaya Y.
MONATSHEFTE FUR CHEMIE, cilt.148, sa.6, ss.1085-1094, 2017 (SCI-Expanded)
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Yayın Türü:
Makale / Tam Makale
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Cilt numarası:
148
Sayı:
6
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Basım Tarihi:
2017
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Doi Numarası:
10.1007/s00706-016-1894-4
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Dergi Adı:
MONATSHEFTE FUR CHEMIE
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Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Sayfa Sayıları:
ss.1085-1094
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Anahtar Kelimeler:
Mannich reaction, Biginelli reaction, Organocatalysis, Green chemistry, Quantum chemical calculations, ONE-POT SYNTHESIS, MULTICOMPONENT BIGINELLI REACTION, ACIDIC IONIC LIQUID, SOLVENT-FREE, EFFICIENT SYNTHESIS, PYRIMIDINONE DERIVATIVES, AROMATIC-ALDEHYDES, GREEN SYNTHESIS, CATALYST, DIHYDROPYRIMIDINONES
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Bursa Uludağ Üniversitesi Adresli:
Evet
Özet
Easily accessible 1-hexadecyl-1H-imidazol-3-ium oxalate is highly efficient Bronsted type acidic catalyst for the selected multicomponent one-pot reactions. The short reaction times, easy workup procedures, and green metal-free conditions for the reactions make the protocols more advantageous. Further reactions proceeded smoothly in good to excellent yields with high purity. To investigate mechanism of the multicomponent reactions, DFT calculations were performed.