SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL HIGHER C,N-DIPHENYL NITRONES, ISOXAZOLINES, AND MERCAPTOBENZIMIDAZOLES AS OLEOCHEMICALS


Yildirim A. , Cetin M.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.187, no.8, pp.952-964, 2012 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 187 Issue: 8
  • Publication Date: 2012
  • Doi Number: 10.1080/10426507.2012.657312
  • Title of Journal : PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Page Numbers: pp.952-964

Abstract

Some novel long-chain nitrones, isoxazolines, and (1H-benzo[d]-imidazol-2-ylthio) derivatives were synthesized. Nitrones, N-{4-[2-(tetradecylthio) acetoxy] benzylidene} aniline oxide, and N-[4-(12-oxo-2,5,8,11-tetraoxadocosan-22-yloxy)benzylidene]aniline oxide were prepared via the reaction of beta-phenylhydroxylamine with the corresponding aromatic aldehydes. The isoxazolines were prepared from undec-10-en-1-ol and benzonitrile-N-oxide which was generated in situ. The 1H-benzo[d]-imidazol-2-ylthio derivatives were synthesized via the replacement reaction of omega-bromo esters and 2-mercaptobenzimidazole.