SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL HIGHER C,N-DIPHENYL NITRONES, ISOXAZOLINES, AND MERCAPTOBENZIMIDAZOLES AS OLEOCHEMICALS

Yildirim, AYHAN; Cetin, M.

doi:10.1080/10426507.2012.657312

SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL HIGHER C,N-DIPHENYL NITRONES, ISOXAZOLINES, AND MERCAPTOBENZIMIDAZOLES AS OLEOCHEMICALS

Atıf İçin Kopyala

Yildirim A., Cetin M.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.187, sa.8, ss.952-964, 2012 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 187 Sayı: 8
Basım Tarihi: 2012
Doi Numarası: 10.1080/10426507.2012.657312
Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.952-964
Bursa Uludağ Üniversitesi Adresli: Evet

Özet

Some novel long-chain nitrones, isoxazolines, and (1H-benzo[d]-imidazol-2-ylthio) derivatives were synthesized. Nitrones, N-{4-[2-(tetradecylthio) acetoxy] benzylidene} aniline oxide, and N-[4-(12-oxo-2,5,8,11-tetraoxadocosan-22-yloxy)benzylidene]aniline oxide were prepared via the reaction of beta-phenylhydroxylamine with the corresponding aromatic aldehydes. The isoxazolines were prepared from undec-10-en-1-ol and benzonitrile-N-oxide which was generated in situ. The 1H-benzo[d]-imidazol-2-ylthio derivatives were synthesized via the replacement reaction of omega-bromo esters and 2-mercaptobenzimidazole.