[Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)], a new two-dimensional coordination polymer involving three simultaneously bridging ligands: 1,2-bis(4-pyridyle)ethene, acetate, and thiocyanate


Morsali A., YILMAZ V. T. , Kazak C.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol.631, no.9, pp.1577-1579, 2005 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 631 Issue: 9
  • Publication Date: 2005
  • Doi Number: 10.1002/zaac.200400550
  • Journal Name: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.1577-1579

Abstract

A new mercury(II) complex of 1,2-bis(4-pyridyle)ethene (bpe) with anionic acetate and thiocyanate ligands has been synthesized and characterized by elemental analysis, IR, H-1 NMR and C-13 NMR spectroscopy. The single crystal X-ray analysis shows that the complex is a two-dimensional polymer with simultaneously bridging 1,2-bis(4-pyridyle)ethane, acetate and thiocyanate ligands and basic repeating dimeric [Hg-2(mu-bpe)(mu-OAc)(2)(mu-SCN)(2)] units. The two-dimensional system forms a three-dimensional network by packing via pi-pi stacking interactions.