(2,2 '-bipyridine)saccharinatosilver(I)


Yilmaz V. T. , Hamamci S., Harrison W. T. A.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.63, 2007 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 63
  • Publication Date: 2007
  • Doi Number: 10.1107/s160053680705845x
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
  • Journal Indexes: Science Citation Index Expanded, Scopus

Abstract

The title complex, [Ag(C7H4NO3S)(C10H8N2)], has a mononuclear structure in which the Ag-I ion is coordinated by two N atoms from 2,2 '-bipyridine and one N atom from saccharinate, forming a distorted T-shaped (or trigonal-planar) AgN3 arrangement. The bite angle of bpy is 71.69 (6)degrees, which contributes significantly to the distortion of the coordination geometry. Molecules are connected by C-H center dot center dot center dot O and pi(bpy)-pi(bpy) interactions with a centroid-centroid separation of 3.6741 (13) angstrom.