Metallic magnesium: an efficient catalyst toward N-aryl and N-alkyl substituted amides directly from aliphatic carboxylic acids

Yildirim A.

MONATSHEFTE FUR CHEMIE, cilt.146, sa.6, ss.947-951, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 146 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1007/s00706-014-1387-2
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.947-951
  • Anahtar Kelimeler: Direct amidation, Amines, Carboxylic acids, Catalysis, Magnesium, ONE-POT, AMINES, CONVERSION, ESTERS, AMIDATION, ANILIDES, SURFACTANTS, ACYLATION, REAGENT
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

An efficient and inexpensive procedure for direct conversion of aliphatic carboxylic acids into amides has been developed using anilines or aliphatic amines and Mg(0) as catalyst in toluene. The amides were obtained by single crystallization in moderate to excellent yields with high purity.