Fractionation and speciation of Cu, Zn and Fe in wine samples by atomic absorption spectrometry

Karadjova I., Izgi B., Gucer S.

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, cilt.57, sa.3, ss.581-590, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 3
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1016/s0584-8547(01)00386-x
  • Dergi Adı: SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.581-590
  • Anahtar Kelimeler: fractionation, speciation, Fe, Cu, Zn, atomic absorption spectrometry, wine, ION-SELECTIVE ELECTRODE, METAL SPECIATION, HEAVY-METALS, FLAME, ALUMINUM, COPPER
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

A scheme is presented for fractionation of wine components and Fe, Cu and Zn determination in different fractions. The charge of the metal species was established using cation and anion exchange separation based on solid phase extraction. The resin XAD-8 was used for the separation of wine polyphenols in complexes with wine proteins and polysaccharides. Dowex ion exchange resins were used for the separation of cationic and anionic species of Fe, Cu and Zn. Flame atomic absorption spectrometry and electrothermal atomic absorption spectrometry were used off-line for the quantitative determination of metals in the different fractions obtained. (C) 2002 Elsevier Science B.V. All rights reserved.