TETRAHEDRON LETTERS, vol.56, no.25, pp.3902-3904, 2015 (SCI-Expanded)
Article / Article
Science Citation Index Expanded (SCI-EXPANDED), Scopus
Oxidation, Oximes, Reaction mechanism, Hammett correlation, Isonitroso hydrogen, PARENT CARBONYL-COMPOUNDS, ONE-POT SYNTHESIS, PREPARATIVE CONVERSION, OXIMES, EFFICIENT, REGENERATION, DERIVATIVES, NITRATE
Bursa Uludag University Affiliated:
Anhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes. (C) 2015 Elsevier Ltd. All rights reserved.