Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene

Erden I., Gronert S., Cabrera G., Coskun N., Tapken M.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, cilt.2017, sa.20, ss.2925-2931, 2017 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2017 Sayı: 20
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1002/ejoc.201700442
  • Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2925-2931
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

The title compound exhibits a number of modes of reactivity toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6-(chloromethyl)-6-methylfulvene with oxygen and nitrogen nucleophiles and bases as well as a carbon-based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound.