Development and application of a solid phase extraction method for the determination of phthalates in artificial saliva using new synthesised microspheres

OSMAN, BİLGEN; Ozer, ELİF; Besirli, Necati; Gucer, Seref

doi:10.1016/j.polymertesting.2013.03.017

Development and application of a solid phase extraction method for the determination of phthalates in artificial saliva using new synthesised microspheres

OSMAN B., Ozer E., Besirli N., Gucer S.

POLYMER TESTING, cilt.32, sa.4, ss.810-818, 2013 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 32 Sayı: 4
Basım Tarihi: 2013
Doi Numarası: 10.1016/j.polymertesting.2013.03.017
Dergi Adı: POLYMER TESTING
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.810-818
Anahtar Kelimeler: Phthalate, Gas chromatography mass spectrometry poly(EGDMA-MATrp), Saliva, Central composite design, CHROMATOGRAPHY-MASS-SPECTROMETRY, DIETHYL PHTHALATE, ACTIVATED CARBON, AQUEOUS-PHASE, ESTERS, MICROEXTRACTION, MIGRATION, PLASTICIZERS, ADSORPTION, PRODUCTS
Bursa Uludağ Üniversitesi Adresli: Evet

Özet

This paper describes a method for the determination of six phthalate esters (PEs) in artificial saliva using solid phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS). A new material was developed to isolate the PEs from artificial saliva. Poly(ethylene glycol dimethacrylate-N-methacryloyl-L-tryptophan methyl ester) (poly(EGDMA-MATrp)) microspheres (average diameter = 106-300 mu m) were synthesised and characterised.