A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization


ÇOLAK A. T. , Irez G., MUTLU GENÇKAL H. , HÖKELEK T., Caylak N.

JOURNAL OF COORDINATION CHEMISTRY, vol.62, no.6, pp.1005-1014, 2009 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 62 Issue: 6
  • Publication Date: 2009
  • Doi Number: 10.1080/00958970802345831
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.1005-1014

Abstract

A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.