3 alpha-Tosyloxymethyltropane(N-8-B)-borane

Batsanov, AS; Howard, JAK; O'Hagan, D; TAVASLI, MUSTAFA

doi:10.1107/s0108270100013019

3 alpha-Tosyloxymethyltropane(N-8-B)-borane

Batsanov A., Howard J., O'Hagan D., TAVASLI M.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.56, 2000 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 56
Basım Tarihi: 2000
Doi Numarası: 10.1107/s0108270100013019
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Bursa Uludağ Üniversitesi Adresli: Hayır

Özet

The title compound [alternative name: 8-methyl-8-azabicyclo[3.2.1]octan-3-ylmethyl p-toluenesulfonate(N-8-B)-borane], C16H26BNO3S, has the tosyloxymethyl substituent in an endo position. The BH3 group is equatorial and the (N-bonded) methyl group is axial, relative to the six-membered heterocycle. The N-B bond of 1.649 (8) Angstrom is one of the longest known.