Reactivity of benzylic acylammonium chlorides. A novel method for the synthesis of N-phenacylamides.

Coskun N., Tirli F.

SYNTHETIC COMMUNICATIONS, cilt.27, sa.1, ss.1-9, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 1
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00397919708004799
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1-9
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

Tertian amines 1 reacted with acid chlorides 2 to give corresponding benzyl chlorides and N-phenacylamides 4. Counterion in species 3 attacked preferentially the benzylic methylene. Effect of substituents in the benzyl group on the reactivity. of acylammonium chlorides 3 was investigated.