BIS[TRIS(2-HYDROXYETHYL)AMINE]NICKEL(II) CHLORIDE


ICBUDAK H., YILMAZ V. T. , HOWIE R., ANDAC O., OLMEZ H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.51, pp.1759-1761, 1995 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 51
  • Publication Date: 1995
  • Doi Number: 10.1107/s0108270195001600
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Page Numbers: pp.1759-1761

Abstract

The crystal structure of bis(2,2',2 '' -nitrilotriethanol-N,O,O')nickel(II) chloride, [Ni(C6H15NO3)(2)]Cl-2, has been determined from X-ray intensity data. The structure consists of an [Ni(C6H15NO3)(2)](2+) cation and two Cl- anions. The central Ni atom in the cation is coordinated by two 2,2/,2 ''-nitrilotriethanol ligands, with bonds to four O atoms and two N atoms resulting in a distorted octahedral environment. The N atoms occupy trans positions and the O3 atom does not coordinate the Ni atom. The Cl anions form three strong intermolecular hydrogen bonds with the hydroxy H atoms of different cations.