[N-(2-Hydroxyethyl)ethylenediamine-kappa N-3,N ',O]-cis-bis(isothiocyanato-kappa N)-copper(II)

Pasaoglu, H; Karadag, AHMET; Tezcan, F; Buyukgungor, O

doi:10.1107/s0108270104033803

[N-(2-Hydroxyethyl)ethylenediamine-kappa N-3,N ',O]-cis-bis(isothiocyanato-kappa N)-copper(II)

Pasaoglu H., Karadag A., Tezcan F., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.61, 2005 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 61
Basım Tarihi: 2005
Doi Numarası: 10.1107/s0108270104033803
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Compendex, EMBASE, INSPEC, MEDLINE
Bursa Uludağ Üniversitesi Adresli: Hayır

Özet

In the novel transition metal isothiocyanate complex of N-(2-hydroxyethyl)ethylenediamine (hydet-en) with copper, [Cu(NCS)(2)(C4H12N2O)], the Cu atom lies in a distorted square-pyramidal environment, coordinated by four N atoms in the basal plane and an apical O atom. The hydet-en ligand is N,N,O-tridentate, in contrast to the disposition in previously studied complexes, while the isothiocyanate ions act as N-atom donor ligands. The monomeric units are linked to one another by hydrogen bonds.