Removal of diethyl phthalate from aqueous phase using magnetic poly(EGDMA-VP) beads

Ozer E., OSMAN B., KARA A., Besirli N., Gucer S., Sozeri H.

JOURNAL OF HAZARDOUS MATERIALS, vol.229, pp.20-28, 2012 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 229
  • Publication Date: 2012
  • Doi Number: 10.1016/j.jhazmat.2012.05.037
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.20-28
  • Keywords: Diethyl phthalate, Removal, Adsorption, Barium hexaferrite, Magnetic beads, HEAVY-METAL IONS, ACTIVATED CARBON, ADSORPTION, KINETICS, WATER, EQUILIBRIUM, CU(II), RESIN, CHITOSAN, ISOTHERM
  • Bursa Uludag University Affiliated: Yes


The barium hexaferrite (BaFe12O19) containing magnetic poly(ethylene glycol dimethacrylate-vinyl pyridine), (mag-poly(EGDMA-VP)) beads (average diameter =53-212 mu m) were synthesized and characterized. Their use as an adsorbent in the removal of diethyl phthalate (DEP) from an aqueous solution was investigated. The mag-poly( EGDMA-VP) beads were prepared by copolymerizing of 4-vinyl pyridine (VP) with ethylene glycol dimethacrylate (EGDMA). The mag-poly(EGDMA-VP) beads were characterized by N-2 adsorption/desorption isotherms (BET), vibrating sample magnetometer (VSM). X-ray powder diffraction (XRD), elemental analysis, scanning electron microscope (SEM) and swelling studies. At a fixed solid/solution ratio, the various factors affecting the adsorption of DEP from aqueous solutions such as pH, initial concentration, contact time and temperature were analyzed. The maximum DEP adsorption capacity of the mag-poly(EGDMA-VP) beads was determined as 98.9 mg/g at pH 3.0, 25 degrees C. All the isotherm data can be fitted with both the Langmuir and the Dubinin-Radushkevich isotherm models. The pseudo first-order, pseudo-second-order. Ritch-second-order and intraparticle diffusion models were used to describe the adsorption kinetics. The thermodynamic parameters obtained indicated the exothermic nature of the adsorption. The DEP adsorption capacity did not change after 10 batch successive reactions, demonstrating the usefulness of the magnetic beads in applications. (C) 2012 Elsevier B.V. All rights reserved.