An efficient catalytic method for fulvene synthesis

Coskun N., Erden I.

TETRAHEDRON, vol.67, no.45, pp.8607-8614, 2011 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 67 Issue: 45
  • Publication Date: 2011
  • Doi Number: 10.1016/j.tet.2011.09.036
  • Journal Name: TETRAHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.8607-8614
  • Keywords: Fulvenes, LFER studies, Green synthesis, Catalysis, Cyclopentadiene, DIELS-ALDER REACTIONS, ALLENE OXIDE, EXCEPTIONALLY SIMPLE, SINGLET OXYGEN, CHEMISTRY, ENDOPEROXIDES, RESONANCE
  • Bursa Uludag University Affiliated: Yes

Abstract

The effects of the nature and amount of base, substrate structure, amount of added water and solvent on the condensation of carbonyl compounds with cyclopentadiene in the presence of secondary amines were investigated. Based on these studies, a new efficient and green synthesis of fulvenes was developed. (C) 2011 Elsevier Ltd. All rights reserved.