trans-Diaquabis[2-(2-pyridyl)ethanol-kappa N-2,O]zinc(II) disaccharinate

Hamamci S., YILMAZ V. T., Thone C.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.58, 2002 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 58
  • Publication Date: 2002
  • Doi Number: 10.1107/s1600536802010887
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
  • Bursa Uludag University Affiliated: No

Abstract

In the title complex, [Zn(C7H11NO2)(2)](C7H4NO3S)(2), the Zn-II ion lies on a crystallographic inversion centre and possesses an octahedral geometry with two neutral 2-pyridylethanol (pyet) ligands and two coordinated water molecules. Pyet acts as an N,O-bidentate ligand, giving rise to a six-membered chelate ring. H atoms of the water molecules and the hydroxy group of pyet are involved in hydrogen bonding with amine-N, sulfonyl-O and carbonyl-O atoms of neighbouring saccharinate ions, creating a three-dimensional network.