A Novel Reaction of alpha-Carbonyl Oxime and Amido Alcohol: Synthesis, Characterization, Crystal Structure, and Thermal Studies of an Amido Alcohol, a New Oximino Alcohol Ligand, and its Metal Complexes


Kaya Y., Irez G., MUTLU GENÇKAL H. , BÜYÜKGÜNGÖR O.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.41, no.7, pp.754-762, 2011 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 41 Issue: 7
  • Publication Date: 2011
  • Doi Number: 10.1080/15533174.2011.591300
  • Title of Journal : SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Page Numbers: pp.754-762

Abstract

In this study, a novel reaction was observed between isonitrosoacetophenone and 1-phenylethanol amine. Acetophenone was used as a starting material to synthesize isonitrosoacetophenone by reaction of acetophenone with n-butyl nitrite in the presence of sodium ethoxide and to synthesize 1-phenylethanol amine by reduction of isonitrosoacetophenone with LiAlH4 in diethyl ether. When the isonitrosoacetophenone reacted with 1-phenylethanol amine, (3E)-3-aza-5-(hydroxyimino)1,4-diphenylpent-3-en-1-ol monohydrate, a new oximino alcohol ligand and amido alcohol were obtained as associated product interestingly. Four complexes were prepared by treatment of oximino alcohol with metal salts such as Cu-II, Ni-II, Zn-II, and Co-II. Amido alcohol was characterized by single-crystal x-ray diffraction, and all complexes were characterized by using spectroscopic techniques and thermogravimetric analysis (TGA).