New alkoxyzinc salts mediated chemoselective transesterification reactions\

Coskun N., Er M.

TURKISH JOURNAL OF CHEMISTRY, cilt.29, sa.5, ss.455-461, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29 Sayı: 5
  • Basım Tarihi: 2005
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.455-461
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

A new chemoselective method for the transesterification of alkyl esters in the presence of in situ formed alkoxyzinc salts was developed. Electron-rich esters are less reactive than electron poor ones and this is the basis for the chemoselectivity of the reaction. Suggested mechanisms of the transesterification reactions are discussed.