Binary potential loop electrodeposition and corrosion resistance of Cr coatings

Kus E., ŞAFAK HACIİSMAİLOĞLU M., ALPER M.

Journal of Applied Electrochemistry, cilt.54, sa.12, ss.2871-2886, 2024 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 54 Sayı: 12
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1007/s10800-024-02135-7
  • Dergi Adı: Journal of Applied Electrochemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Aquatic Science & Fisheries Abstracts (ASFA), Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.2871-2886
  • Anahtar Kelimeler: Binary potential loop, Chromium, Corrosion, Cr coating, Electrodeposition
  • Bursa Uludağ Üniversitesi Adresli: Evet

Özet

This work aims to electrodeposit Cr from a solution containing only Cr3+ ions but not any other complexing, buffering and pH agents, and study its corrosion behavior. The solution was investigated by cyclic voltammetry and ultraviolet–visible spectroscopy. It was obtained that it is rich in native Cr complexes including Cl. Cr was successfully coated from this solution by binary potential loop electrodeposition. First, − 0.7 V potential was applied for a time interval ranging from 5 to 30 s. Then, a − 1.8 V potential was applied to deposit the Cr layer with the thickness changed from 50 to 1000 nm. X-ray diffraction patterns showed that all films are in a bcc crystal structure. The Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy and optical profilometry measurements inferred that the coatings include hydrated-Cl complexes mostly edges of the coating and cracks. The scanning electron microscopy images indicated that the cracks on the surface are tiny for the layers thinner than 500 nm but prominent for the layers thicker than 500 nm. The corrosion behavior was examined by electrochemical impedance spectroscopy and Tafel measurements. The coatings electrodeposited by the binary potential loop had a corrosion rate lower and resistance higher than those of the coatings electrodeposited at − 1.8 V potential. The corrosion parameters became superior for the coatings with layers thinner than 500 nm and the aged ones. Graphical abstract: (Figure presented.)