Nanopowders and single crystal of new Pb(II) three-dimensional coordination polymer, [Pb(H2O)(mu-OAc)(mu-sac)(n), "PASAC" were synthesized by a sonochemical and branched tube methods (Yilmaz et al., Z. Anorg. Allg. Chem. 629 (2003) 172). The new nano-structures of Pb(II) coordination polymer were characterized by X-ray crystallography analysis, scanning electron microscopy (SEM), X-ray powder diffraction (XRD), surface analysis (BET), and IR spectroscopy. The crystal structure of these compounds consists of three-dimensional polymeric units. The thermal stability of compounds was studied by thermal gravimetric analysis (TGA) and differential thermal analyses (DTA). PbS and PbO nano-structures were obtained by calcinations of the nano-structures of this coordination polymer at 600 degrees C. (C) 2014 Elsevier B.V. All rights reserved.