trans-Bis(diethanolamine)bis(isothio-cyanato)nickel(II)
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.56, ss.948-949, 2000 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 56
- Basım Tarihi: 2000
- Doi Numarası: 10.1107/s0108270100007289
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.948-949
- Bursa Uludağ Üniversitesi Adresli: Hayır
Özet
In the neutral title complex, trans-bis(2,2'-iminodiethanol-N,O)bis(isothiocyanato)nickel(II), [Ni(NCS)(2)(C4H11NO2)(2)], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The Ni-II ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and N-NCS- Ni-N-amine and N-NCS -Ni-O-amine bond angles of 88.78 (10) and 89.44 (10)degrees, respectively. The Ni-N bond distances are in the range 2.069 (3)-2.096 (2) Angstrom. The molecules are linked by hydrogen bonds to form a three-dimensional infinite lattice.